Trueblood, Jonathan V.; Estillore, Armando D.; Lee, Christopher; Dowling, Jacqueline A.; Prather, Kimberly A.; Grassian, Vicki H. (2017). Data from: Heterogeneous Chemistry of Lipopolysaccharides with Gas-Phase Nitric Acid: Reactive Sites and Reaction Pathways. In Center for Aerosol Impacts on Chemistry of the Environment (CAICE). UC San Diego Library Digital Collections. https://doi.org/10.6075/J0ST7N0C

Publication abstract: Recent studies have shown that sea spray aerosol (SSA) has a size-dependent, complex composition consisting of biomolecules and biologically derived organic
compounds in addition to salts. This additional chemical complexity most likely influences the heterogeneous reactivity of SSA, as these other components will have different reactive
sites and reaction pathways. In this study, we focus on the reactivity of a class of particles derived from some of the biological components of sea spray aerosol including lipopolysaccharides (LPS) that undergo heterogeneous chemistry within the reactive sites of the biological molecule. Examples of these reactions and the relevant reactive sites are proposed as follows: R−COONa(s) + HNO₃(g) → NaNO₃ + R−COOH and R−HPO₄Na(s) + HNO₃(g) → NaNO₃ + R−H₂PO₄. These reactions may be a heterogeneous pathway not only for sea spray aerosol but also for a variety of other types of atmospheric aerosol as well.

This package contains data and an explanatory readme file for Raman and ATOFMS results in “Heterogeneous Chemistry of Lipopolysaccharides with Gas-Phase Nitric Acid: Reactive Sites and Reaction Pathways”.

• Time period of project: 2014-07-01 to 2016-07-01

• 2017

• Trueblood, Jonathan V.

• Dowling, Jacqueline A.
• Estillore, Armando D.
• Grassian, Vicki H.
• Lee, Christopher
• Prather, Kimberly A.
• Trueblood, Jonathan V.

• Grassian, Vicki H.

• Heterogeneous chemistry
• Lipopolysaccharide
• Raman spectroscopy
• Reaction pathways
• Sea spray aerosol (SSA)

• data

Doi: https://doi.org/10.6075/J0ST7N0C

Primary associated publication

• Trueblood, J. V; Estillore, A. D.; Lee, C.; Dowling, J. A.; Prather, K. A.; Grassian, V. H. Heterogeneous Chemistry of Lipopolysaccharides with Gas-Phase Nitric Acid : Reactive Sites and Reaction Pathways. J. Phys. Chem. A. (2016). 120, 6444–6450. https://doi.org/10.1021/acs.jpca.6b07023

Other version

• Alternate project file location: https://doi.org/10.4246/caice-jtrueblood_vgrassian_jpca2016_20170512_jtrueblood_vgrassian_jpca2016md588c6028103fd48972bb1e3558dbeffb4.zip

Creative Commons Attribution 4.0 International Public License

• UC Regents

Under copyright (US)

Use: This work is available from the UC San Diego Library. This digital copy of the work is intended to support research, teaching, and private study.

Constraint(s) on Use: This work is protected by the U.S. Copyright Law (Title 17, U.S.C.). Use of this work beyond that allowed by "fair use" or any license applied to this work requires written permission of the copyright holder(s). Responsibility for obtaining permissions and any use and distribution of this work rests exclusively with the user and not the UC San Diego Library. Inquiries can be made to the UC San Diego Library program having custody of the work.

Research Data Curation Program, UC San Diego, La Jolla, 92093-0175 (https://lib.ucsd.edu/rdcp )

2023-05-22