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Data from: Genuine Carbene Versus Carbene-Like Reactivity

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Data from: Genuine Carbene Versus Carbene-Like Reactivity

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1 digital object.

Cite This Work

Lorkowski, Jan; Yorkgitis, Patrick; Serrato, Melinda R.; Gembicky, Milan; Pietraszuk, Cezary; Bertrand, Guy; Jazzar, Rodolphe (2024). Data from: Genuine Carbene Versus Carbene-Like Reactivity. UC San Diego Library Digital Collections. https://doi.org/10.6075/J0QZ2B5R

Description

Abstract: Singlet carbenes are not always isolable and often even elude direct detection. When they escape observation, their formation can sometimes be evidenced by in situ trapping experiments. However, is carbene-like reactivity genuine evidence of carbene formation? Herein, using the first example of a spectroscopically characterized cyclic (amino)(aryl)carbene (CAArC), we cast doubt on the most common carbene trapping reactions as sufficient proof of carbene formation.

Creation Date
  • 2023-04 to 2023-11
Date Issued
  • 2024
Authors
Principal Investigator
Co Principal Investigator
Funding

This work was supported by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, Catalysis Science Program, under Award # DE-SC0009376 (G.B) and the Agence Nationale de la Recherche, under Award # ANR-20-CE07-0000-cResolu (R.J.). We also acknowledge the Kościuszko Foundation, Iwanowska program No PPN/IWA/2018/1/00015 of Polish National Agency for Academic Exchange, the National Science Centre (Poland) project UMO-2015/19/N/ST5/00538 (J.L.), and the Keck Foundation for computational resources.

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Language
  • English
Identifier

Identifier: Cesary Pietrazuk: http://orcid.org/0000-0003-2413-0478

Identifier: Guy Bertrand: https://orcid.org/0000-0003-2623-2363

Identifier: Jan Lorkowski: https://orcid.org/0000-0003-3436-1296

Identifier: Melinda Serrato: https://orcid.org/0000-0002-4069-628X

Identifier: Milan Gembicky: https://orcid.org/0000-0002-3898-1612

Identifier: Patrick Yorkgitis: https://orcid.org/0000-0002-5285-0184

Identifier: Rodolphe Jazzar: https://orcid.org/0000-0002-4156-7826

Related Resources

    Primary associated publication

    • Lorkowski, J., Yorkgitis, P., Serrato, M. R., Gembicky, M., Pietraszuk, C., Bertrand, G., and Jazzar, R. Genuine Carbene Versus Carbene-Like Reactivity. Angew. Chem. Int. Ed. 2024, e202401020. https://doi.org/10.1002/anie.202401020

    Collection image

    • Image source: Jan Lorkowski and Rodolphe Jazzar. "Graphical Abstract."

Data from: Genuine Carbene Versus Carbene-Like Reactivity
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